Hydrophilization and hydrophobization of the surface of solids with the help of SAA

1. Hydrophilization and hydrophobization of the surface of solids with the help of SAA

Done by: Mussina, Orazalina

2. What is hydrophobization of surfaces?

What is
hydrophobizatio
n of surfaces?

3. What is hydrophilization of surfaces?

Hydrophilization of the surface means a stable
significant increase in polarity, which persists even
after the evaporation of water. Such a change in
polarity is achieved by a more radical interference
in the nature of the surface layer when the chemical
composition of the surface macromolecules
changes.
The surface hydrophilization also reduces the
average adhesion force, but to a lesser extent than
hydrophobization. A similar decrease in the average
adhesion strength during hydrophilization is
observed in the air.

4. Hydrophilization of surfaces by surfactants

When the surface is hydrophilized
under the influence of surfactant,
the wetting work increases with
increasing surfactant
concentration in the solution. This
indicates a decrease in the
interfacial tension at the T-G
interface due to adsorption and an
increase in the affinity of the liquid
to a given surface.
Surface-active substances are
chemical compounds, which,
concentrating on the interface of
thermodynamic phases, cause a
decrease in surface tension

5. Hydrophobization of surface by surfactant

The effect of hydrophobization
is based on the adsorption of
surfactants on the surface of
the rock, improving the
wettability of its oil and,
consequently, increasing the
phase permeability for oil. This
contributes to an increase in
the flow rate of oil and a
reduction in the water cut of
the extracted products.

6. Adsorption of SAA on solid surface

SAA- surface active agents.
e adsorption of these
molecules at the solid-liquid
interface depends on several
factors such as the nature of
the substrate, solvent,
adsorbate species, the
presence of secondary
competing-cooperative
species, temperature and
even mode of mixing.

7.

Adsorption phenomena in the case of solids are
usually studied on powders, S specific surface area
which is determined independently (usually by
adsorptiongases'.) In this case, as a rule, determine
the number of substances Г* absorbed by the unit of
mass of powder, Г*= ∆сV/M1
where ∆с –the change of concentration in volume of
solution V, M1- mass of powder. Here value of
absorption equals to
Г= Г*/S

8.

In accordance with the rule of the greatest adsorption
polarity equalizationability to have a surfactant with an
intermediate (between solid and liquid)polarity. An
essential feature of adsorption on solids is the
possibility ofthe formation of chemical bonds between
surfactant molecules and a solid.
We use SAA for:
1) for hydrophilization and hydrophobication solid
surfaces.
2) process control wetting and selective wettings.

9.

Adsorption of surfactants on
solid particles from solutions,
gives the adsorption at the
interface of the air / liquid
environment, that is,
radically changes the size of
the edge angle.
тж
cos
жг
тг

10.

Surfactants are divided into two main
groups – ionogenic and nonionic.
Towards the group ionogenic include
surfactants, polar groups of which
dissociate in the aquatic environment.
Ionogenic surfactant, in turn, are
subdivided into anionic and cationic
surfactants. Cationic surfactants are the
polar group of which receives a positive
charge, and anionic-negative. There is
also a group of amphoteric surfactants,
in molecules which contain both cationic
and anionic groups.

11. Thank you for your attention!